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1 article(s) from Cobb, Steven L

¹⁹F NMR as a tool in chemical biology

Diana Gimenez,
Aoife Phelan,
Cormac D. Murphy and
Steven L. Cobb

Beilstein J. Org. Chem. 2021, 17, 293–318, doi:10.3762/bjoc.17.28

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Graphical Abstract

Figure 1: Selected examples of ¹⁹F-labelled amino acid analogues used as probes in chemical biology.

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Figure 2: (a) Sequences of the antimicrobial peptide MSI-78 and pFtBSer-containing analogs and cartoon repres...

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Figure 3: (a) Chemical structures of a selection of trifluoromethyl tags. (b) Comparative analysis showing th...

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Figure 4: (a) First bromodomain of Brd4 with all three tryptophan residues displayed in blue and labelled by ...

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Figure 5: (a) Enzymatic hydroxylation of GBBNF in the presence of hBBOX (b) ¹⁹F NMR spectra showing the conve...

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Figure 6: (a) In-cell enzymatic hydrolysis of the fluorinated anandamide analogue ARN1203 catalyzed by hFAAH....

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Figure 7: (a) X-ray crystal structure of CAM highlighting the location the phenylalanine residues replaced by...

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Figure 8: ¹⁹F PREs of 4-F, 5-F, 6-F, 7-FTrp49 containing MTSL-modified ^S52CCV-N. The ¹⁹F NMR resonances of ox...

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Figure 9: ¹⁹F NMR as a direct probe of Ud NS1A ED homodimerization. Schematic representation showing the loca...

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Figure 10: (a) Representative spectrum of a 182 μM sample of Aβ1-40-tfM35 at varying times indicating the majo...

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Figure 11: Illustration of the conformational switch induced by SDS in 4-tfmF-labelled α-Syn. Also shown are t...

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Figure 12: (a) Structural models of the Myc‐Max (left), Myc‐Max‐DNA (middle) and Myc‐Max‐BRCA1 complexes (righ...

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Figure 13: (a) Side (left) and bottom (right) views of the pentameric apo ELIC X-ray structure (PDB ID: 3RQU) ...

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Figure 14: (a) General structure of a selection of recently developed ¹⁹F-labelled nucleotides for their use a...

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Figure 15: Monitoring biotransformation of the fluorinated pesticide cyhalothrin by the fungus C. elegans. The...

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Figure 16: Following the biodegradation of emerging fluorinated pollutants by ¹⁹F NMR. The spectra are from cu...

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Figure 17: Discovery of new fluorinated natural products by ¹⁹F NMR. The spectrum is of the culture supernatan...

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Figure 18: Application of ¹⁹F NMR to investigate the biosynthesis of nucleocidin. The spectra are from culture...

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Figure 19: Detection of new fluorofengycins (indicated by arrows) in culture supernatants of Bacillus sp. CS93...

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Figure 20: Measurement of β-galactosidase activity in MCF7 cancer cells expressing lacZ using ¹⁹F NMR. The deg...

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Figure 21: Detection of ions using ¹⁹F NMR. (a) Structure of TF-BAPTA and its ¹⁹F iCEST spectra in the presenc...

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Figure 22: (a) The ONOO⁻-mediated decarbonylation of 5-fluoroisatin and 6-fluoroisatin. The selectivity of (b)...

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Review

Published 28 Jan 2021

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19F NMR as a tool in chemical biology

¹⁹F NMR as a tool in chemical biology